Constant volume: $V = 60\,\text{L}$ (inflow = outflow).
(a) Differential equation:
In rate: $0.4\,\text{kg/L} \times 5\,\text{L/min} = 2\,\text{kg/min}$
Out rate: $\dfrac{q}{60}\,\text{kg/L} \times 5\,\text{L/min} = \dfrac{q}{12}\,\text{kg/min}$
\[ q' = 2 - \dfrac{q}{12}, \quad q(0) = 0 \]
(b) Solution:
Standard form: $q' + \dfrac{1}{12}q = 2$
Integrating factor: $\mu(t) = e^{t/12}$
\[ (e^{t/12}q)' = 2e^{t/12} \]
\[ e^{t/12}q = 24e^{t/12} + C \]
\[ q = 24 + Ce^{-t/12} \]
Apply $q(0) = 0$: $0 = 24 + C \Rightarrow C = -24$
\[ q(t) = 24(1 - e^{-t/12}) \]
(c) Time when concentration = 0.25 kg/L:
Concentration $c = \dfrac{q}{60} = 0.25 \Rightarrow q = 15\,\text{kg}$
\[ 24(1 - e^{-t/12}) = 15 \]
\[ 1 - e^{-t/12} = \dfrac{15}{24} = \dfrac{5}{8} \]
\[ e^{-t/12} = \dfrac{3}{8} \]
\[ -\dfrac{t}{12} = \ln\left(\dfrac{3}{8}\right) \]
\[ t = -12\ln\left(\dfrac{3}{8}\right) \approx 11.77\,\text{min} \]
\[ \boxed{q' = 2 - \dfrac{q}{12},\ q(0)=0} \]
\[ \boxed{q(t) = 24(1 - e^{-t/12})} \]
\[ \boxed{t \approx 11.77\,\text{min}} \]